Product ID:LITHIUM/MANGANESE DIOXIDE BATTERY DL2032
MSDS Date:10/25/1989
FSC:6135
NIIN:01-210-8715
Status Code:A
MSDS Number: CKQWR

DURACELL INC TECHNICAL SALES AND MARKETING GROUP

BERKSHIRE CORPORATE PARK
BETHEL, CT 06801
US

Emergency Phone: 203-736-4000

Info Phone: 203-796-4000

Cage: 90303

DURACELL INC TECHNICAL SALES AND MARKETING GROUP

BETHEL, CT 06801 US

Telephone: 203-796-4000

Cage: 90303

LITHIUM

CAS: 7439-93-2

RTECS: OJ5540000

MANGANESE DIOXIDE (MNO2)

CAS: 1313-13-9

RTECS: OP0350000

OSHA PEL C5 MG/M3

ACGIH TLV: 5 MG/M3

GRAPHITE (SYNTHETIC, GR)

CAS: 7782-42-5

RTECS: MD9659600

OSHA PEL SEE TABLE Z-3

ACGIH TLV: 2 MG/M3

PROPYLENE CARBONATE (PC)

CAS: 108-32-7

RTECS: FF9650000

DIMETHOXYETHANE OR 1,2-DIMETHOXYETHANE

CAS: 110-71-4

RTECS: KI1451000

LITHIUM PERCHLORATE (LICLO4)

CAS: 7791-03-9

LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:THESE CHEMICALS ARE IN A SEALED CAN.
RISK OF EXPOSURE OCCURS ONLY IF THE BATTERY IS MECHANICALLY OR
ELECTRICALLY ABUSED. THE MOST LIKELY RISK IS ACUTE EXPOSURE WHEN A
CELL VENTS. PC IS MILDLY IRRITATI NG ON SYE AND SKIN CONTACT. DME
IS BELIEVED TO BE SLIGHTLY TO MODERATELY TOXIC. CONTACT OF
ELECTROLYTE AND EXTRUDED LITHIUM WITH SKIN AND EYES SHOULD BE
AVOIDED.
Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Effects of Overexposure:IRRITATION OF SKIN AND EYES. LITHIUM CAN CAUSE
THERMAL AND CHEMICAL BURNS UPON CONTACT WITH THE SKIN. DMA MAY BE A
REPRODUCTIVE HAZARD.
Medical Cond Aggravated by Exposure:AN ACUTE EXPOSURE WILL NOT
GENERALLY AGGRAVATE ANY MEDICAL ATTENTION.

First Aid:IN CASE OF SKIN CONTACT WITH CONTENTS OF BATTERY, FLUSH
IMMEDIATELY WITH WATER. FOR EYE CONTACT, FLUSH WITH COPIOUS AMOUNTS
OF WATER FOR 15 MINUTES. DO NOT INHALE VENTED MATERIAL. IF
IRRITATION PERSIS TS, GET MEDICAL HELP.

Flash Point Method:OC
Flash Point:=57.2C, 135.F
PC
Lower Limits:2.3 (PC)
Extinguishing Media:WATER.
Fire Fighting Procedures:THE PREFERRED PROCEDURE IS TO RAPIDLY COOL THE
BATTERIES AND ADJACENT STRUCTURES WITH WATER.
Unusual Fire/Explosion Hazard:CELLS CAN VENT WHEN SUBJECTED TO
EXCESSIVE HEAT. WHEN LARGE NUMBERS OF CELLS ARE INVOLVED IN A FIRE,
FIRE FIGHTERS SHOULD USE SCBA.

Spill Release Procedures:THE PREFERRED RESPONSE IS TO LEAVE THE AREA
AND ALLOW BATTERIES TO COOL AND VAPORS DISSAPATE. AVOID SKIN AND
EYE CONTACT OR INHALATION OF VAPORS. REMOVE SPILLED LIQUID WITH
ABSORBENT AND INCINERATE. P REFERABLY, CLEAN UP CREW SHOULD WEAR
FULL-FACE RESPIRATOR (PARTICULATE/ORGANIC VAPOR CARTIDGE).
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.

Handling and Storage Precautions:AVOID MECHANICAL OR ELECTRICAL ABUSE.
Other Precautions:BATTERIES MAY EXPLODE, PYROLIZE OR VENT IF
DISASSEMBLED, CRUSHED, RECHARGED OR EXPOSED TO FIRE OR HIGH
TEMPERATURE. DO NOT SHORT OR INSTALL WITH INCORRECT POLARITY.

Respiratory Protection:SCBA (FIRE); FULL-FACE RESPIRATOR WITH
PARTICULATE/ORGANIC CARTIDGE (SPILL).
Ventilation:IN CASE OF VENTING, PROVIDE AS MUCH VENTILATION AS
POSSIBLE.
Protective Gloves:BUTYL.
Eye Protection:SAFTEY GLASSES.
Other Protective Equipment:NONE.
Work Hygienic Practices:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Supplemental Safety and Health
NO DATA PROVIDED BY RESPONSIBLE PARTY.

HCC:Z6
Boiling Pt:=242.C, 467.6F
B.P. Text:PC
Melt/Freeze Pt:=180.C, 356.F
M.P/F.P Text:LI
Vapor Pres:0.03 (PC)
Vapor Density:3.1 DME
Spec Gravity:0.54 (LI)
Evaporation Rate & Reference:4.99 (DME)
Solubility in Water:MODERATE (PC)
Appearance and Odor:PC IS COLORLESS/ODORLESS LIQUID. MNO2/GRAPHITE ARE
BLACK POWDERS.

Stability Indicator/Materials to Avoid:YES
NO DATA PROVIDED BY RESPONSIBLE PARTY.
Stability Condition to Avoid:DO NOT HEAT, DISASSEMBLE OR RECHARGE.
Hazardous Decomposition Products:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION WILL NOT
OCCUR.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPROPRIATE
REGULATIONS. OPEN CELLS SHOULD BE TREATED AS HAZARDOUS WASTE.

Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY.

Transport Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.

SARA Title III Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Federal Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.